The use of fly ash formed in the CFBC technology to study the efficiency of heavy metal ion removal from municipal wastewater
Key words:
fly ash, the CFBC technology, water quality, adsorption, heavy metals, wastewater treatment
Summary
Fly ash has been examined for the effectiveness of removing Cu(II), Cd(II), Ni(II), Pb(II) and Zn(II) metal ions from municipal wastewater. Fly ash is cheap waste resulting from the combustion of municipal sewage sludge by means of circulating fluidized bed combustion (CFBC) technology. This adsorbent has been characterized for organoleptic and physicochemical properties using selected methods, such as fraction analysis, bulk density, particle size distribution, elemental composition (SEM-EDS), thermogravimetry, texture using BET adsorption isotherms, specific surface area, pore volume, average pore diameter, BJH pore volume distribution, morphology using scanning electron microscope (SEM), ATR FT-IR.
Based on the results obtained, the following reduction of heavy metal ions concentration in municipal wastewater samples was demonstrated: Cu - 66.7%, Zn - 61.5%, Ni - 61.1%, Cd - 49.4%, Pb - 47.9%. In summary, fly ash obtained in CFBC technology is a promising low-cost adsorbent for the effective removal of metals from municipal wastewater and can be considered for practical industrial applications in the future.
Dr inż. Tomasz KALAK
Dr inż. Anna KŁOPOTEK
Poznan University of Economics and Business
Institute of Quality Science
Department of Industrial Products and Packaging Quality
Aleja Niepodleglosci 10, 61-875 Poznań, Poland
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